Year : 
1984
Title : 
Chemistry
Exam : 
JAMB Exam

Paper 1 | Objectives

1 - 10 of 45 Questions

# Question Ans
1.

Sodium chloride may be obtained from brine by

A. titration

B. decantation

C. distillation

D. evaporation

E. sublimation

D

2.

20 cm 3 of hydrogen gas are sparked with 20cm 3 of oxygen gas in an endimoeter at 373k (100 oC) and 1 atmosphere. The resulting mixture is cooled to 298 K (25 oC) and passed over calcium chloride. The volume of the residual gas is

A. 40 cm 3

B. 20 cm 3

C. 30 cm 3

D. 10cm 3

E. 5cm 3

Detailed Solution

2H2 + O2 ------2H2O
2V 1V 2V
20cm3 20cm3 -------
20cm3 10cm3 20cm3
Residual gas = 20cm3 - 10cm3 of 02 = 103
3.

For the reaction NH4NO2 \(\to\) N2 + 2H2O, calculate the volume of nitrogen that would be produced at S. T. P from 3.2 g of the dioxonitrate(iii)salt. (Relative atomic masses: N = 14, O = 16, H = 1)

A. 2.24 dm 3

B. 2.24 cm3

C. 123

D. 12dm 3

E. 48 dm 3

Detailed Solution

\(NH_{4}NO_{2}\) \(\to\) \(N_{2}\) + \(2H_{2}O\)
\(64g\) \(\to\) \(22.4dm^{3}\)
\(3.2g\) will give \(\frac{22.4}{64}\) \(\times\) \(\frac{3.2}{64}\)
= \(1.12dm^{3}\)
4.

A molar solution of caustic soda is prepared by dissolving

A. 40 g NaOH in 100 g of water

B. 40 g NaOH in 1000 g of water

C. 20 g NaOH in 500 of solution

D. 20 g NaOH in 1000 g of solution

E. 2o g NaOH in 80 g of solution

Detailed Solution

A molar solution implies concentration in terms of moles/liter. The respective atomic weights for NaOH are: Na - 23,0 - 16 and H - 1, so the molecular weight, is 23 + 16 + I = 40. Thus 40 grams of NaOH equals one mole of NaOH, and a 1 molar solution of NaOH will contain 40 grams of NaOH chemical in 1000grams of water.
5.

Which among the elements 1. Carbon 2. Oxygen 3. Copper 4. Bromine 5. Zinc, will NOT react with either water or steam?

A. 1 and 2

B. 2 and 3

C. 3 and 4

D. 1, 2, and 3

E. 2, 3, and 5

B

6.

Naphthalene when heated melts at 354 K (81 oC). At this temperature the molecules of naphthalene

A. decompose into smaller molecules

B. change their shape

C. are oxidized by atmospheric oxygen

D. contract

E. become mobile as the inter molecular forces are broken

E

7.

The ratio of the number of molecules in 2g of hydrogen to that in 16g of oxygen is

A. 2:1

B. 1:1

C. 1:2

D. 1:4

E. 1:8

A

8.

The balanced equation for the reaction of tetraoxosulphate(VI)acid with aluminium hydroxide to give water and aluminium tetraoxosulphate(VI) is

A. H2SO4 + Al(OH)2 \(\to\) 2H2O + AlSO4

B. 3H2SO4 + 2Al(OH)3 \(\to\) 6H2O + Al2(SO4)3

C. 3H2SO4 + 2AlH \(\to\) 6H2O + Al(SO4)3

D. 3H2 SO4 + 2Al(OH)3 \(\to\) Al(SO4)3

E. H2SO4 + Al(OH)3 \(\to\) H2O + Al2(SO4)3

B

9.

Which of the following mixtures would result in a solution of pH greater than 7?

A. 25.00 cm3 of 0.05 M H2SO4 and 25.00cm3 of 0.50 M Na2CO3

B. 25.00 cm3 of 0.05 M H2SO4 and 25.00 cm3 of 0.10 M NaHCO3

C. 10 M NaOH

D. 25.00cm3 of 0.11 MH2 SO4 and 50.00 cm3 of 0.05 M NaOH

E. 25.00cm3 of 0.25 M H2SO4 and 50.00cm3 of 0.20 M NaOH

A

10.

In which of the following reactions does hydrogen peroxide act as a reducing agent?

A. H2S + H2O2 \(\to\) S + 2H2O

B. PbSO3 + H2O2 \(\to\) PbSO4 + H2O

C. 2I+ 2H+ + H2O2 \(\to\) I2 + 2H2O

D. PbO2 + 2HNO3 + H2O2 \(\to\) Pb(NO3)2 + 2H2O + O2

E. SO2 + H2O2 \(\to\) H2SO4

D

1.

Sodium chloride may be obtained from brine by

A. titration

B. decantation

C. distillation

D. evaporation

E. sublimation

D

2.

20 cm 3 of hydrogen gas are sparked with 20cm 3 of oxygen gas in an endimoeter at 373k (100 oC) and 1 atmosphere. The resulting mixture is cooled to 298 K (25 oC) and passed over calcium chloride. The volume of the residual gas is

A. 40 cm 3

B. 20 cm 3

C. 30 cm 3

D. 10cm 3

E. 5cm 3

Detailed Solution

2H2 + O2 ------2H2O
2V 1V 2V
20cm3 20cm3 -------
20cm3 10cm3 20cm3
Residual gas = 20cm3 - 10cm3 of 02 = 103
3.

For the reaction NH4NO2 \(\to\) N2 + 2H2O, calculate the volume of nitrogen that would be produced at S. T. P from 3.2 g of the dioxonitrate(iii)salt. (Relative atomic masses: N = 14, O = 16, H = 1)

A. 2.24 dm 3

B. 2.24 cm3

C. 123

D. 12dm 3

E. 48 dm 3

Detailed Solution

\(NH_{4}NO_{2}\) \(\to\) \(N_{2}\) + \(2H_{2}O\)
\(64g\) \(\to\) \(22.4dm^{3}\)
\(3.2g\) will give \(\frac{22.4}{64}\) \(\times\) \(\frac{3.2}{64}\)
= \(1.12dm^{3}\)
4.

A molar solution of caustic soda is prepared by dissolving

A. 40 g NaOH in 100 g of water

B. 40 g NaOH in 1000 g of water

C. 20 g NaOH in 500 of solution

D. 20 g NaOH in 1000 g of solution

E. 2o g NaOH in 80 g of solution

Detailed Solution

A molar solution implies concentration in terms of moles/liter. The respective atomic weights for NaOH are: Na - 23,0 - 16 and H - 1, so the molecular weight, is 23 + 16 + I = 40. Thus 40 grams of NaOH equals one mole of NaOH, and a 1 molar solution of NaOH will contain 40 grams of NaOH chemical in 1000grams of water.
5.

Which among the elements 1. Carbon 2. Oxygen 3. Copper 4. Bromine 5. Zinc, will NOT react with either water or steam?

A. 1 and 2

B. 2 and 3

C. 3 and 4

D. 1, 2, and 3

E. 2, 3, and 5

B

6.

Naphthalene when heated melts at 354 K (81 oC). At this temperature the molecules of naphthalene

A. decompose into smaller molecules

B. change their shape

C. are oxidized by atmospheric oxygen

D. contract

E. become mobile as the inter molecular forces are broken

E

7.

The ratio of the number of molecules in 2g of hydrogen to that in 16g of oxygen is

A. 2:1

B. 1:1

C. 1:2

D. 1:4

E. 1:8

A

8.

The balanced equation for the reaction of tetraoxosulphate(VI)acid with aluminium hydroxide to give water and aluminium tetraoxosulphate(VI) is

A. H2SO4 + Al(OH)2 \(\to\) 2H2O + AlSO4

B. 3H2SO4 + 2Al(OH)3 \(\to\) 6H2O + Al2(SO4)3

C. 3H2SO4 + 2AlH \(\to\) 6H2O + Al(SO4)3

D. 3H2 SO4 + 2Al(OH)3 \(\to\) Al(SO4)3

E. H2SO4 + Al(OH)3 \(\to\) H2O + Al2(SO4)3

B

9.

Which of the following mixtures would result in a solution of pH greater than 7?

A. 25.00 cm3 of 0.05 M H2SO4 and 25.00cm3 of 0.50 M Na2CO3

B. 25.00 cm3 of 0.05 M H2SO4 and 25.00 cm3 of 0.10 M NaHCO3

C. 10 M NaOH

D. 25.00cm3 of 0.11 MH2 SO4 and 50.00 cm3 of 0.05 M NaOH

E. 25.00cm3 of 0.25 M H2SO4 and 50.00cm3 of 0.20 M NaOH

A

10.

In which of the following reactions does hydrogen peroxide act as a reducing agent?

A. H2S + H2O2 \(\to\) S + 2H2O

B. PbSO3 + H2O2 \(\to\) PbSO4 + H2O

C. 2I+ 2H+ + H2O2 \(\to\) I2 + 2H2O

D. PbO2 + 2HNO3 + H2O2 \(\to\) Pb(NO3)2 + 2H2O + O2

E. SO2 + H2O2 \(\to\) H2SO4

D