Year : 
1991
Title : 
Chemistry
Exam : 
JAMB Exam

Paper 1 | Objectives

1 - 10 of 49 Questions

# Question Ans
1.

Which of the following can be obtained by fractional distillation?

A. Nitrogen from liquid air

B. Sodium chloride from sea water

C. Iodine from a solution of Iondine in carbon tetrachloride

D. Sulphur from a solution of sulphur incarbon disulphide

A

2.

Which of the following are mixtures?
i, Petroleum
ii, Rubber latex
iii. Vulcanizer's solution
iv, Carbon (II)sulphide

A. i, ii and iii

B. i, ii and iv

C. i and ii only

D. i and iv

A

3.

An iron ore is known to contain 70.0% Fe2O3. The obtain from 80kg of the ore is?

(Fe = 56, O = 16)

A. 35.0 kg

B. 39.2 kg

C. 70.0 kg

D. 78.4 kg

Detailed Solution

2Fe2O3 → 4Fe + 3O2
320g 224g 96g
(70) / (100) x (80) / (1) 56g
if 0.32kg of Fe293 contains 0.224 kg
Then 56kg will contain (56 x 0.224) / (0.32) =39.2 kg
4.

In two separate experiments, 0.36g and 0.71g of chlorine combined with a metal X to give Y and Z respectively. An analysis showed that Y and Z contain 0.20g and 0.40g of X respectively. The data above represents the law of ?

A. multiple proportion

B. conservation of mass

C. constant composition

D. reciprocal proportion

Detailed Solution

0.36g of Cl combines with 0.2g of x

1g of Cl will combine with \(\frac{1 \times 0.2}{0.32}\) = 0.56

0.71g of U combines with 0.49g of x

1g of U will combine with \(\frac{1 \times 0.4}{71}\) = 0.56

Ratio 0.56 : 0.56 = 1:1
5.

30cm\(^3\) of oxygen at 10 atmospheres pressure is placed in a 20 cm\(^3\) container. Calculate the new pressure if temperature is kept constant?

A. 6.7 atm

B. 15.0 atm

C. 60.0 atm

D. 0 atm

Detailed Solution

P\(_1\)V\(_1\) = P\(_2\)V\(_2\) (where T is kept constant)
30 x 10 = P\(_2\) x 20
P\(_2\) = \(\frac{30 \times 10}{20}\)
= 15.0 atm
6.

Calculate the volume of carbon (IV)oxide measured at s.t.p, produced when 1 kg of potassium hydrogen trioxocarbonate (IV) is totally decomposed by heat?

(G.M.V. at s.t.p 22.4 dm3, K = 39, O = 16, C = 12, H = 1)

A. 28 dm3

B. 56 dm3

C. 112 dm3

D. 196 dm3

Detailed Solution

2KHCOdm3 → K2CO3 + H2O + CO2
2(39 + 1 + 12 + 48) 22.4 dm3
200 g 22.4 dm3 of CO2
1000 g (1000) / (200) x 22.4 = 112 dm3
7.

A given quantity of a gas occupies a volume of 228 cm3 at a pressure of 750mm Hg. What will be its volume at atmospheric pressure?

A. 220 cm3

B. 225 cm3

C. 230 cm3

D. 235 cm3

Detailed Solution

P1V1 = P2V2 ∴ 750 x 228 = 760 V2
V2 = (750 x 228 cm3) / (760) = 225 cm3
8.

A sample of a gas exerts a pressure of 8.2 atm when confined in a 2.93 dm3 container at 20°C. The number of moles of gas in the sample is?

(R = 0.082 litre atm / deg mole)

A. 1.00

B. 2.00

C. 3.00

D. 4.00

Detailed Solution

PV = nRT
2.93 x 8.2 = 0.082 x 293 xn
∴ n = (2.93 x8.2) / (0.082 x 293)
n = 1
9.

Atoms of element X (with 2 electrons in the outer shell). combine with atoms of Y (with 7 electrons in the outer shell). Which of the following statements is FALSE? The compound formed?

A. has formula XY

B. is likely to be ionic

C. contains X2+ ions

D. contains Y- ions

Detailed Solution

The compound formed by a mixture of X and Y will be \(XY_{2}\) not XY.
10.

The electronic configuration of an elements is 1s22s22p63s23p3. How many unpaired electrons are there in the element?

A. 5

B. 4

C. 3

D. 2

C

1.

Which of the following can be obtained by fractional distillation?

A. Nitrogen from liquid air

B. Sodium chloride from sea water

C. Iodine from a solution of Iondine in carbon tetrachloride

D. Sulphur from a solution of sulphur incarbon disulphide

A

2.

Which of the following are mixtures?
i, Petroleum
ii, Rubber latex
iii. Vulcanizer's solution
iv, Carbon (II)sulphide

A. i, ii and iii

B. i, ii and iv

C. i and ii only

D. i and iv

A

3.

An iron ore is known to contain 70.0% Fe2O3. The obtain from 80kg of the ore is?

(Fe = 56, O = 16)

A. 35.0 kg

B. 39.2 kg

C. 70.0 kg

D. 78.4 kg

Detailed Solution

2Fe2O3 → 4Fe + 3O2
320g 224g 96g
(70) / (100) x (80) / (1) 56g
if 0.32kg of Fe293 contains 0.224 kg
Then 56kg will contain (56 x 0.224) / (0.32) =39.2 kg
4.

In two separate experiments, 0.36g and 0.71g of chlorine combined with a metal X to give Y and Z respectively. An analysis showed that Y and Z contain 0.20g and 0.40g of X respectively. The data above represents the law of ?

A. multiple proportion

B. conservation of mass

C. constant composition

D. reciprocal proportion

Detailed Solution

0.36g of Cl combines with 0.2g of x

1g of Cl will combine with \(\frac{1 \times 0.2}{0.32}\) = 0.56

0.71g of U combines with 0.49g of x

1g of U will combine with \(\frac{1 \times 0.4}{71}\) = 0.56

Ratio 0.56 : 0.56 = 1:1
5.

30cm\(^3\) of oxygen at 10 atmospheres pressure is placed in a 20 cm\(^3\) container. Calculate the new pressure if temperature is kept constant?

A. 6.7 atm

B. 15.0 atm

C. 60.0 atm

D. 0 atm

Detailed Solution

P\(_1\)V\(_1\) = P\(_2\)V\(_2\) (where T is kept constant)
30 x 10 = P\(_2\) x 20
P\(_2\) = \(\frac{30 \times 10}{20}\)
= 15.0 atm
6.

Calculate the volume of carbon (IV)oxide measured at s.t.p, produced when 1 kg of potassium hydrogen trioxocarbonate (IV) is totally decomposed by heat?

(G.M.V. at s.t.p 22.4 dm3, K = 39, O = 16, C = 12, H = 1)

A. 28 dm3

B. 56 dm3

C. 112 dm3

D. 196 dm3

Detailed Solution

2KHCOdm3 → K2CO3 + H2O + CO2
2(39 + 1 + 12 + 48) 22.4 dm3
200 g 22.4 dm3 of CO2
1000 g (1000) / (200) x 22.4 = 112 dm3
7.

A given quantity of a gas occupies a volume of 228 cm3 at a pressure of 750mm Hg. What will be its volume at atmospheric pressure?

A. 220 cm3

B. 225 cm3

C. 230 cm3

D. 235 cm3

Detailed Solution

P1V1 = P2V2 ∴ 750 x 228 = 760 V2
V2 = (750 x 228 cm3) / (760) = 225 cm3
8.

A sample of a gas exerts a pressure of 8.2 atm when confined in a 2.93 dm3 container at 20°C. The number of moles of gas in the sample is?

(R = 0.082 litre atm / deg mole)

A. 1.00

B. 2.00

C. 3.00

D. 4.00

Detailed Solution

PV = nRT
2.93 x 8.2 = 0.082 x 293 xn
∴ n = (2.93 x8.2) / (0.082 x 293)
n = 1
9.

Atoms of element X (with 2 electrons in the outer shell). combine with atoms of Y (with 7 electrons in the outer shell). Which of the following statements is FALSE? The compound formed?

A. has formula XY

B. is likely to be ionic

C. contains X2+ ions

D. contains Y- ions

Detailed Solution

The compound formed by a mixture of X and Y will be \(XY_{2}\) not XY.
10.

The electronic configuration of an elements is 1s22s22p63s23p3. How many unpaired electrons are there in the element?

A. 5

B. 4

C. 3

D. 2

C